Abstract
A new micro-solid phase extraction method was developed by combining solid-phase extraction and stir bar sorptive extraction to benefit from the advantages of both techniques. A polypyrrole coating was electrochemically synthesized on the surface of an already used graphite furnace, employed in electro-thermal atomic absorption spectroscopy. The cylindrical geometry of the graphite tube provided a rather huge surface area, suitable for sorptive extraction. The novel sorbent coating was examined as an extracting medium to isolate malathion. Effects of different parameters such as extraction time, salt concentration, sample volume, desorption solvent and time were investigated and optimized. Under the optimized conditions, the limit of detection and limit of quantification of the developed method were 5 and 20 ng L−1, respectively. The calibration curve showed linearity in the range of 0.1–100 μg L−1 (R 2 = 0.9968). The precision was evaluated at 0.1 and 1 μg L−1 concentration levels and relative standard deviations (n = 3) were found to be 10 and 7%, respectively. The developed method was successfully applied to the extraction of malathion from real river water and tap water samples, and relative recoveries at the spiked level of 0.1 μg L−1 were 94 and 97%, respectively.
References
Farré M, Pérez S, Gonçalves C, Alpendurada MF, Barcelo D (2010) Trends Anal Chem 29:1347–1362
Prieto A, Basauri O, Rodil R, Usobiaga A, Fernández LA, Etxebarria N, Zuloaga O (2010) J Chromatogr A 1217:2642–2666
Portugal FCM, Pinto ML, Nogueira JMF (2008) Talanta 77:765–773
Chaves AR, Silva MS, Queiroz RHC, Lanças FM, Queiroz MEC (2007) J Chromatogr B 850:295–302
Wu J, Pawliszyn J (2004) Anal Chim Acta 520:257–264
Bagheri H, Saraji M (2003) J Chromatogr A 986:111–119
Bagheri H, Mohammadi A, Salemi A (2004) Anal Chim Acta 513:445–449
Bagheri H, Mir A, Babanezhad E (2005) Anal Chim Acta 532:89–95
Bagheri H, Mohammadi A (2003) J Chromatogr A 1015:23–30
The British Crop Protection Council (2000) e-Pesticide manual, version 2, 12th edn. Wise and Loveys information services Ltd, Herts
Thompson TS, Treble RG, Magliocco A, Roettger JR, Eichhorst JC (1998) Forensic Sci Int 95:89–98
Bonner MR, Coble J, Aaron Blairl A, Freeman LEB, Hoppin JA, Sandler DP, Alavanja MCR (2007) Am J Epidemiol 166:1023–1034
Bavcon M, Trebše P, ZupančIč-Kralj L (2003) Chemosphere 50:595–601
Sabik H, Jeannot R (2000) J Chromatogr A 879:73–82
Zulin Z, Huasheng H, Xinhong W, Jianqing L, Weiqi C, Li X (2002) Mar Pollut Bull 45:397–402
Sanz CP, Halko R, Ferrera ZS, Rodríguez JJS (2004) Anal ChimActa 524:265–270
López FJ, Pitarch E, Egea S, Beltran J, Hernández F (2001) Anal Chim Acta 433:217–226
Ng WF, Teo MJK, Lakso HA (1999) Fresenius J Anal Chem 363:673–679
Bagheri H, Babanezhad E, Khalilian F (2009) Anal Chim Acta 634:209–214
Mohammadi A, Yamini Y, Alizadeh N (2005) J Chromatogr A 1063:1–8
Bagheri H, Saraji M (2001) J Chromatogr A 910:87–93
Olszowy P, Szultka M, Ligor T, Nowaczyk J, Buszewski B (2010) J Chromatogr B 878:2226–2234
Uğur T, Yücel Ş, Nusret E, Yasemin U, Kadir P, Attila Y (2004) J Electroanal Chem 570:6–12
Kaykhaii M, Saffari F (2008) J Sci Islam Repub Iran 19:111–117
Pawliszyn J (2009) Handbook of solid phase microextraction. Chemical industry press, China
Bagheri H, Khalilian F, Naderi M, Babanezhad E (2010) J Sep Sci 33:1132–1138
Filho AM, dos Santos FN, de P Pereira PA (2010) Microchem J 96:139–145
Martínez Vidal JL, Pablos Espada MC, Garrido Frenich A, Arrebola FJ (2000) J Chromatogr A 867:235–245
Peñalver A, García V, Pocurull E, Borrull F, Marce RM (2003) J Chromatogr A 1007:1–9
Acknowledgments
The Research Council and Graduates School of Sharif University of Technology (SUT) are thanked for supporting the project. Also, we would like to acknowledge the Iran National Elite Foundation for their support for Ali Aghakhani.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bagheri, H., Aghakhani, A., Ayazi, Z. et al. A Polypyrrole-Based Sorptive Microextraction Coating for Preconcentration of Malathion from Aquatic Media. Chromatographia 74, 731–735 (2011). https://doi.org/10.1007/s10337-011-2130-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10337-011-2130-3